Viktor
V. Zhdankin
Professor
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PERSONAL DATA: BORN: Russia; Naturalized US Citizen since 1999 ADDRESS: Department of Chemistry and Biochemistry, 1038 University Drive, University of Minnesota Duluth, Duluth, MN 55812 TELEPHONE: Office - (218) 726-6902; FAX: (218) 726-7394 |
EDUCATION:
Doctor of Science (the highest scientific degree in Russia): 1987, Department of Chemistry, Moscow State University, Moscow, Russia
Ph.D. (Russian analog): 1981, Department of Chemistry, Moscow State University, Moscow, Russia Advisor: Professor Nikolai S. Zefirov
B.S./M.S. (Russian
analog): 1978, Department
of Chemistry, Moscow State
University, Moscow, Russia
ACADEMIC EXPERIENCE:
Professor, Department of Chemistry, University of Minnesota Duluth, July 1999 - present.RESEARCH INTERESTS:
Green and
Sustainable Chemistry: development of catalytic and recyclable
systems based on iodine chemistry.
Exploratory Synthetic Organic Chemistry of Hypervalent Main-Group
Elements: preparation, identification and uses of new organic
derivatives of plolyvalent iodine, bromine, xenon, and phosphorus.
Synthesis of Heterocycles.
Synthetic Organic Chemistry of Fluorine: preparation of
perfluoroalkylated compounds; organic reactions of powerful fluorinating
reagents (XeF2, CsOSO2OF, etc.); synthetic
application of fluoroorganic compounds.
SIGNIFICANT PROFESSIONAL SERVICE AND AWARDS
• National Award of the American Chemical Society for Creative Research & Applications of Iodine Chemistry, 2011TEXTBOOKS:
SELECTED RECENT PUBLICATIONS (click here for full list):
PseudocyclicArylbenziodoxaboroles
as Water-Triggered Aryne Precursors in Reactions with Organic Sulfides.
Yoshimura, A.; Ngo, K.; Mironova, I.A.; Gardner, Z.S.; Rohde, G.T.;
Ogura, N.; Ueki, A.; Yusubov, M.S.; Saito, A.; Zhdankin, V.V. Org.
Lett. 2024, 26,
1891-1895.
Recent
Progress in Synthetic Applications of Hypervalent Iodine(III) Reagents.
Yoshimura, A.; Zhdankin, V.V. Chem.
Rev. 2024, 124,
11108-11186.
Organohypervalent Heterocycles. Kumar, R.; Dohi, T.; Zhdankin, V.V. Chem. Soc. Rev. 2024, 53, 4786-4827.
Generation
of benzyne from aryl benziodoxaborole triflate under aqueous conditions
and its reactions with alkyl aryl sulfides. Yoshimura, A.; Ngo, K.;
Mironova, I.A.; Gardner, Z.S.; Ogura, N.; Ueki, A.; Yusubov, M.S.;
Saito, A.; Zhdankin, V.V. Arkivoc
2024, (i),
202412213.
Preparation
and X‑ray Structural Study of Dibenzobromolium and Dibenzochlorolium
Derivatives. Huss, C.D.; Yoshimura, A.; Rohde, G.T.; Mironova, I.A.;
Postnikov, P.S.; Yusubov, M.S.; Saito, A.; Zhdankin, V.V. ACS
Omega 2024, 9,
2664–2673.
Peptide
coupling using recyclable bicyclic benziodazolone. Uehara, D.; Adachi,
S.; Tsubouchi, A.; Okada, Y.; Zhdankin, V.V.; Yoshimura, A.; Saito, A. Chem.
Commun. 2024, 60,
256-259. https://doi.org/10.1039/D3CC05416K.
New Isoxazole-Substituted Aryl Iodides: Metal-Free Synthesis, Characterization and Catalytic Activity. Rimi, R.; Uttam, B.; Zhdankin, V.V.; Kumar, R. Eur. J. Org. Chem. 2024, e202301191.
Front
Cover Article: New Isoxazole-Substituted Aryl Iodides: Metal-Free
Synthesis, Characterization and Catalytic Activity. Rimi, R.; Uttam, B.;
Zhdankin, V.V.; Kumar, R. Eur. J.
Org. Chem. 2024, issue
5. DOI: https://doi.org/10.1002/ejoc.202400092.
Recent Progress in Synthetic Applications of Cyclic Hypervalent Iodine(III) Reagents. Yoshimura, A.; Saito, A.; Zhdankin, V.V. Adv. Synth. Cat. 2023, 365, 2653-2675. (Very Important Publication).
Front
Cover Picture for Special Issue: Iodine in Catalysis and Organic
Synthesis. Recent Progress in Synthetic Applications of Cyclic
Hypervalent Iodine(III) Reagents. Yoshimura, A.; Saito, A.; Zhdankin,
V.V. Adv. Synth. Cat. 2023,
365, 2651.
Aryl-,
Akynyl-, and Alkenylbenziodoxoles: Synthesis and Synthetic Applications.
Mironova, I.A.; Noskov, D.M.; Yoshimura, A.; Yusubov, M.S.; Zhdankin,
V.V. Molecules 2023,
28, 2136.
Dehydrogenative Cycloisomerization/Arylation Sequence of N-Propargyl Carboxamides with Arenes by Iodine(III)-Catalysis. Umakoshi, Y.; Takemoto, Y.; Tsubouchi, A.; Zhdankin, V.V.; Yoshimura, A.; Saito, A. Adv. Synth. Cat. 2022, 364, 2053-2059. (Very Important Publication)
Hypervalent
Iodine-Mediated Azidation Reactions. Mironova, I.A.; Kirsch, S.F.;
Zhdankin, V.V.; Yoshimura, A.; Yusubov, M.S. Eur.
J. Org. Chem. 2022,
e202200754.
Zwitterionic Iodonium Species Afford Halogen Bond-Based Porous Organic Frameworks. Soldatova, N.S.; Postnikov, P.S.; Ivanov, D.M.; Semyonov, O.V.; Kukurina, O.S.; Guselnikova, O.; Yamauchid, Y.; Wirth, T.; Zhdankin, V.V.; Yusubov, M.S.; Gomila, R.M.; Frontera, A.; Resnati, G.; Kukushkin, V.A. Chem. Sci. 2022, 13, 5650-5658.
Synthesis
of 2-fluorobenzoic acids by nucleophilic fluorination of
1-arylbenziodoxolones. Ozerskaya, A.V.; Larkina, M.S.; Podrezova, E.V.;
Svitich, D.Yu.; Yusubova, R.Yu.; Zhdankin, V.V.; Yusubov, M.S. ARKIVOC
2022, (vii),
108-125.
Hypervalent
iodine (V) catalyzed reactions. Soni, S.; Rimi, Kumar, V.; Kikushima,
K.; Dohi, T.; Zhdankin, V.V.; Kumar, R. ARKIVOC 2022,
(vii), 27-56.
Introduction to hypervalent iodine chemistry. Zhdankin, V.V. ARKIVOC 2022, (vii), 1-6.
Recyclable
Hypervalent Iodine Reagents in Modern Organic Synthesis. Rimi; Soni, S.;
Uttam, B.; China, H.; Dohi, T.; Zhdankin, V.V.; Kumar, R. Synthesis
2022, 54,
2731-2748.
Chapter 1. Historical Introduction. Zhdankin, V.V. Iodine Catalysis in Organic Synthesis. Ishihara, K.; Muniz, K. Eds., Wiley-VCH, Weinheim, Germany, 2022.
Preparation and synthetic applicability of imidazole-containing cyclic iodonium salts. Antonkin, N.; Vlasenko, Y.; Yoshimura, A.; Smirnov, V.; Borodina, T.; Zhdankin, V.V.; Yusubov, M.S.; Shafir, A.; Postnikov, P. J. Org. Chem. 2021, 86, 7163-7178.
Zefirov’s reagent and related hypervalent iodine triflates. Yusubov, M.S.; Zhdankin, V.V. Mendeleev Commun. 2021, 31, 282–287.
2-Iodosylbenzoic acid activated by trifluoromethanesulfonic anhydride: efficient oxidant and electrophilic reagent for preparation of iodonium salts. Yoshimura, A.; Huss, C.D.; Saito, A.; Kitamura, T.; Zhdankin, V.V. New J. Chem. 2021, 45, 16434-16437.
Aryne
cycloaddition reaction as a facile and mild modification method for
design of electrode materials for high-performance symmetric
supercapacitor. Sviridova, E.; Li, M.; Barras, A.; Addad, A.; Yusubov,
M.S.; Zhdankin, V.V.; Yoshimura, A.; Szunerits, S.; Postnikov, P.S.;
Boukherroub, R. Electrochimica Acta,
2021, 369,
137667.
Preparation, structure, and reactivity of pseudocyclic btrifluorosulfonyloxy vinylbenziodoxolone derivatives. Yoshimura, A.; Huss, C.D.; Liebl, M.; Rohde, G.T.; Larson, S.M.; Frahm, G.B.; Luedtke, M.W.; Schumacher, T.J.; Gardner, Z.S.; Zhdankin, V.V.; Postnikov, P.S.; Yusubov, M.S.; Kitamura, T.; Saito, A. Adv. Synth. Cat. 2021, 363, 3365-3371.
Convenient Synthesis of Benziodazolone: New Reagents for Direct Esterification of Alcohols and Amidation of Amines. Shea, M.T.; Rohde, G.T.; Vlasenko, Yu.A.; Postnikov, P.S.; Yusubov, M.S.; Zhdankin, V.V.; Saito, A.; Yoshimura, A. Molecules 2021, 26, 7355-7373.
Hypervalent iodine compounds: reagents of the future. Zhdankin, V.V. ARKIVOC 2020, (iv), 1-11.
Synthesis of Oxazoline and Oxazole Derivatives by Hypervalent Iodine-Mediated Oxidative Cycloaddition Reactions. Yoshimura, A.; Saito, A.; Yusubov, M.S.; Zhdankin, V.V. Synthesis 2020, 52, 2299-2310.
Fluorocyclization of N-Propargyl Carboxamides by λ3-Iodane Catalysts with Coordinating Substituents. Takahashi, S.; Umakoshi, Y.; Nakayama, K.; Okada, Y.; Zhdankin, V.V.; Yoshimura, A.; Saito, A. Adv. Synth. Cat. 2020, 362, 2997-3003.
Imino-λ3-iodane and Catalytic Amount of I2-Mediated
Synthesis of N-Allylsulfenamides via [2,3]-Sigmatropic Rearrangement.
Makitalo, C.L.; Yoshimura, A.; Rohde, G.T.; Mironova, I.A.; Yusubova,
R.Y.; Yusubov, M.S.; Zhdankin, V.V.; Saito, A. Eur.
J. Org. Chem. 2020,
6433-6439.
Benziodoxole-Derived Organosulfonates: The Strongest Hypervalent Iodine Electrophiles and Oxidants. Yusubov, M.S.; Postnikov, P.S.; Yoshimura, A.; Zhdankin, V.V. Synlett 2020, 31, 315-326.
Hypervalent Iodine(III) Reagent Mediated Regioselective Cycloaddition of Aldoximes with Enaminones. Yoshimura, A.; Jarvi, M.E.; Shea, M.T.; Makitalo, C.L.; Rohde, G.T.; Yusubov, M.S.; Saito, A.; Zhdankin, V.V. Eur. J. Org. Chem. 2019, 6682-6689.
2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(V) oxidant. Yusubov, M.S.; Soldatova, N.S.; Postnikov, P.S.; Valiev, R.R.; Yoshimura, A.; Wirth, T.; Nemykin, V.N.; Zhdankin, V.V. Chem. Commun. 2019, 54, 7760-7763. (highlighted in Chemistry World: https://www.chemistryworld.com/news/new-hypervalent-iodine-compound-is-most-powerful-oxidant-in-series/3010642.article).
Iodonium imides in organic synthesis. Yoshimura, A.; Yusubov, M.S.; Zhdankin, V.V. ARKIVOC 2019, (i), 228-255.
Sulfonylimino Group Transfer Reaction Using Imino-lambda3-iodanes with I2 as Catalyst Under Metal-free Conditions. Yoshimura, A.; Makitalo, C.L.; Jarvi, M.E.; Shea, M.T.; Postnikov, P.S.; Rohde, G.T.; Zhdankin, V.V.; Saito, A.; Yusubov, M.S. Molecules 2019, 24, 979-990.
Iodonium salts as benzyne precursors. Yoshimura, A.; Saito, A.; Zhdankin, V.V. Chem. Eur. J. 2018, 24, 15156-15166.
Preparation and structure of phenolic aryliodonium salts. Yoshimura, A.; Shea, M.T.; Guselnikova, O.; Postnikov, P.S.; Rohde, G.T.; Saito, A.; Yusubov, M.S.; Nemykin, V.N.; Zhdankin, V.V. Chem. Commun. 2018, 53, 10363-10366.
Synthesis of five-membered iodine-nitrogen heterocycles
from benzimidazole-based iodonium salts. Vlasenko, Yu.A.; Postnikov, P.S.;
Trusova, M.E.; Shafir, A.; Zhdankin, V.V.; Yoshimura, A.; Yusubov, M.S. J.
Org. Chem. 2018, 83,
12056-12070.
Reactions of 1-Arylbenziodoxolones with Azide Anion: Experimental and Computational Study of Substituent Effects. Yusubov, M.S.; Soldatova, N.S.; Postnikov, P.S.; Valiev, R.R.; Svitich, D.Y.; Yusubova, R.Y.; Yoshimura, A.; Wirth, T.; Zhdankin, V.V. Eur. J. Org. Chem. 2018, 640-647 (Very Important Paper).
Preparation, Structure, and Reactivity of Bicyclic Benziodazole: New Hypervalent Iodine Heterocycle. Yoshimura, A.; Shea, M.T.; Makitalo, C.L.; Jarvi, M.E.; Rohde, G.T.; Saito, A.; Yusubov, M.S.; Zhdankin, V.V. Beilstein J. Org. Chem. 2018, 14, 1016-1020.
Preparation and X-ray structure of 2-iodoxybenzenesulfonic acid (IBS) – a powerful hypervalent iodine(V) oxidant. Mironova, I.A.; Postnikov, P.S.; Yusubova, R.Y.; Yoshimura, A.; Wirth, T.; Zhdankin, V.V.; Nemykin, V.N.; Yusubov, M.S. Beilstein J. Org. Chem. 2018, 14, 1854-1858.
2-Iodoxybenzoic Acid Tosylates: the Alternative to Dess-Martin Periodinane Oxidizing Reagents. Yusubov, M.S.; Postnikov, P.S.; Yusubova, R.Y.; Yoshimura, A.; Jrjens, G.; Kirschning, A.; Zhdankin, V.V. Adv. Synth. Cat. 2017, 359, 3207-3216.
Hypervalent Iodine Reagent Mediated Oxidative Heterocyclization of Aldoximes with Heterocyclic Alkenes. Yoshimura, A.; Nguyen, K.C.; Rohde, G.T.; Postnikov, P.S.; Yusubov, M.S.; Zhdankin, V.V. J. Org. Chem. 2017, 82, 11742-11751.
Editorial for the Special Issue on Hypervalent Iodine Reagents. Zhdankin, V.V.; Muniz, K. J. Org. Chem. 2017, 82, 11667-11668.
Pseudocyclic Arylbenziodoxaboroles: Efficient Benzyne Precursors Triggered by Water at Room Temperature. Yoshimura, A.; Fuchs, J.M.; Middleton, K.R.; Maskaev, A.V.; Rohde, G.T.; Saito, A.; Postnikov, P.S.; Yusubov, M.S.; Nemykin, V.N.; Zhdankin, V.V. Chem. Eur. J. 2017, 23, 16738-16742.
Development of Imino-λ3-iodanes with Improved Reactivity for Metal-Free [2+2+1] Cycloaddition-Type Reactions. Baba, T.; Takahashi, S.; Kambara, Y.; Yoshimura, A.; Nemykin, V.N.; Zhdankin, V.V.; Saito, A. Adv. Synth. Cat. 2017, 359, 3860-3864.
Iodine(III)-Mediated/Catalyzed Cycloisomerization–Amination Sequence of N-Propargyl Carboxamides. Okamura, Y.; Sato, D.; Yoshimura, A.; Zhdankin, V.V.; Saito, A. Adv. Synth. Cat. 2017, 359, 3243-3247.
Iodine(III)-Catalyzed Formal [2 + 2 + 1] Cycloaddition Reaction for Metal-Free Construction of Oxazoles. Yagyu, T.; Takemoto, Y.; Yoshimura, A.; Zhdankin, V.V.; Saito, A. Org. Lett. 2017, 19, 2506-2509.
Preparation, Structure, and Reactivity of Pseudocyclic Benziodoxole Tosylates: New Hypervalent Iodine Oxidants and Electrophiles. Yoshimura, A.; Klasen, S.C.; Shea, M.T.; Nguyen, K.C.; Rohde, G.T.; Saito, A.; Postnikov, P.S.; Yusubov, M.S.; Nemykin, V.N.; Zhdankin, V.V. Chem. Eur. J. 2017, 23, 691-695.
Catalytic Cycloisomerization-Fluorination Sequence of N-Propargyl Amides by Iodoarene/HF-Pyridine/Selectfluor Systems. Asari, T.; Takemoto, Y.; Shinomoto, Y.; Yagyu, T.; Yoshimura, A.; Zhdankin, V.V.; Saito, A. Asian J. Org. Chem. 2016, 5, 1314-1317. (with cover picture)
Synthetic applications of pseudocyclic hypervalent iodine compounds. Yoshimura, A.; Yusubov, M.S.; Zhdankin, V.V. Org. Biomol. Chem. 2016, 14, 4771-4781.
Advances in Synthetic Applications of Hypervalent Iodine Compounds. Yoshimura, A.; Zhdankin, V.V. Chem. Rev. 2016, 116, 3328-3435.
Hypervalent Heterocycles. Zhdankin, V.V. Advances in Heterocyclic Chemistry, 2016, 119, pp 57-79.
Oxidative Cycloadditon of Aldoximes with Maleimides using Catalytic Hydroxy(aryl)iodonium Species. Yoshimura, A.; Nguyen, K.C.; Rohde, G.T.; Saito, A.; Yusubov, M.S.; Zhdankin, V.V. Adv. Synth. Cat. 2016, 358, 2340-2344.
Hypervalent Iodine Catalyzed Synthesis of 1,2,4-Oxadiazoles from Aldoximes and Nitriles. Yoshimura, A.; Nguyen, K.C.; Klasen, S.C.; Postnikov, P.S.; Yusubov, M.S.; Saito, A.; Nemykin, V.N.; Zhdankin, V.V. Asian J. Org. Chem. 2016, 5, 1128-1133.
Mild and efficient synthesis of iodylarenes using Oxone as oxidant. Soldatova, N.; Postnikov, P.S.; Troyan, A.A.; Yoshimura, A.; Yusubov, M.S.; Zhdankin, V.V. Tetrahedron Lett. 2016, 57, 4254-4256.
Preparation and X-ray structural study of dibenziodolium derivatives. Postnikov, P.S.; Guselnikova, O.A.; Yusubov, M.S.; Yoshimura, A.; Nemykin, V.N.; Zhdankin, V.V. J. Org. Chem. 2015, 80, 5783-5788.
Saccharin-based μ-Oxo Imidoiodane: A Readily Available and Highly Reactive Reagent for Electrophilic Amination. Yoshimura, A.; Koski, S.R.; Fuchs, J.M.; Saito, A.; Nemykin, V.N.; Zhdankin, V.V. Chem. Eur. J. 2015, 21, 5328-5331.
Preparation, Structure, and Versatile Reactivity of Pseudocyclic Benziodoxole Triflate, New Hypervalent Iodine Reagent. Yoshimura, A.; Nguyen, K.C.; Klasen, S.C.; Saito, A.; Nemykin, V.N.; Zhdankin, V.V. Chem. Commun. 2015, 51, 7835-7838.
Iodine catalysis: a green alternative to transition metals in organic chemistry and technology. Yusubov, M. S.; Zhdankin, V. V. Resource-Efficient Technologies (Elsevier) 2015, 1, 49-67.
Tetra-n-butylammonium Iodide-Catalyzed C-H Azidation of Aldehydes with Thermally Stable Azidobenziodoxolone. Shinomoto, Y.; Yoshimura, A.; Shimizu, H.; Yamazaki, M.; Zhdankin, V.V.; Saito, A. Adv. Synth. Cat. 2015, 357, 667-671.
Metal-Free [2+2+1] Annulation of Alkynes, Nitriles and N-Atoms from Iminoiodanes for Synthesis of Highly Substituted Imidazoles. Saito, A.; Kambara, Y.; Yagyu, T.; Noguchi, K.; Yoshimura, A.; Zhdankin, V.V. Org. Lett. 2015, 17, 5212-5215.
Iodine Heterocycles. Zhdankin, V.V. Advances in
Heterocyclic Chemistry, 2015,
115, Ch. 4.
Hypervalent Iodoarenes and Aryliodonium Salts (Update 2014). Zhdankin,
V.V. Science of Synthesis, 2015,
31, Ch. 31.4.1.3.
The I=X (X = O, N, C) Double Bond in Hypervalent Iodine Compounds: Is it Real? Ivanov, A.S.; Popov, I.A.; Boldyrev, A.I.; Zhdankin, V.V. Angew. Chem. Int. Ed. 2014, 53, 9617-9621 (highlighted in Chemistry World: http://www.rsc.org/chemistryworld/2014/07/iodine-double-bonds-dative).
Hypoiodite-Mediated Catalytic Cyclopropanation of Alkenes with Malononitrile. Yoshimura, A.; Jones, T.N.; Yusubov, M.S.; Zhdankin, V.V. Adv. Synth. Cat. 2014, 356, 3336-3340.
Hypoiodite-Mediated Cyclopropanation of Alkenes. Yoshimura, A.; Koski, S.R.; Kastern, B.J.; Fuchs, J.M.; Jones, T.N.; Yusubova, R.Y.; Nemykin, V.N.; Zhdankin, V.V. Chem. Eur. J. 2014, 20, 5895-5898.
Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer: a highly efficient catalyst for biomimetic oxygenation reactions. Yusubov, M.S.; Celik, C.; Geraskina, M.R.; Yoshimura, A.; Zhdankin, V.V.; Nemykin, V.N. Tetrahedron Lett. 2014, 55, 5687-5690.
Development of New Hypervalent Iodine Reagents with Improved Properties and Reactivity by Redirecting Secondary Bonds at Iodine Center. Protasiewicz, J.D.; Zhdankin, V.V. Coord. Chem. Rev. 2014, 275, 54-62.
Synthesis of 1,2,4-thiadiazoles by oxidative dimerization of carbothioamides using Oxone. Yoshimura, A.; Todora, A.D.; Kastern, B.J.; Koski, S.R.; Zhdankin, V.V. Eur. J. Org. Chem. 2014, 5149-5152.
2-Iodoxybenzoic acid organosulfonates: preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(V) oxidants. Yusubov, M.S.; Svitich, D.Yu.; Yoshimura, A.; Nemykin, V.N.; Zhdankin, V.V. Chem. Commun. 2013, 49, 11269-11271.
Hypoiodite mediated synthesis of isoxazolines from aldoximes and alkenes using catalytic KI and Oxone as the terminal oxidant. Yoshimura, A.; Zhu, C.; Middleton, K.R.; Todora, A.D.; Kastern, B.J.; Maskaev, A.V.; Zhdankin, V.V. Chem. Commun. 2013, 49, 4800-4802.
Hypervalent iodine catalyzed generation of nitrile oxides from oximes and their cycloaddition with alkenes or alkynes. Yoshimura, A.; Middleton, K.R.; Todora, A.D.; Kastern, B.J.; Koski, S.R.; Maskaev, A.V.; Zhdankin, V.V. Org. Lett. 2013, 15, 4010-4013.
Applications of iodonium salts and iodonium ylides as precursors for nucleophilic fluorination in Positron Emission Tomography. Yusubov, M.S.; Svitich, D.Yu.; Larkina, M.S.; Zhdankin, V.V. ARKIVOC 2013, (i), 364-395.
Preparation and X-ray Structural Study of 1-Arylbenziodoxolones. Yusubov, M.S.; Yusubova, R.Y.; Nemykin, V.N.; Zhdankin, V.V. J. Org. Chem. 2013, 78, 3767-3773.
Hypervalent Iodine Catalyzed Hofmann Rearrangement of Carboxamides using Oxone as Terminal Oxidant. Yoshimura, A.; Middleton, K.R.; Luedtke, M.W.; Zhu, C.; Zhdankin, V.V. J. Org. Chem. 2012, 77, 11399-11404.
Hypoiodite-Mediated Metal-Free Catalytic Aziridination of Alkenes. Yoshimura, A.; Middleton, K.R.; Zhu, C.; Nemykin, V.N.; Zhdankin, V.V. Angew. Chem. Int. Ed. 2012, 51, 8059-8062.
Hypervalent Iodine Reagents and Green Chemistry. Yusubov, M.S.; Zhdankin, V.V. Curr. Org. Synth. 2012, 9, 247-272.
Design, Preparation, X-ray Crystal Structure, and Reactivity of o-Alkoxyphenyliodonium Bis(methoxycarbonyl)methanide, a Highly Soluble Carbene Precursor. Zhu, C.; Yoshimura, A.; Ji, L.; Wei, Y.; Nemykin, V.N.; Zhdankin, V.V. Org. Lett. 2012, 14, 3170-3173.
New highly soluble dimedone-derived iodonium ylides: preparation, X-ray structure, and reaction with carbodiimide leading to oxazole derivatives. Zhu, C.; Yoshimura, A.; Solntsev, P.; Ji, L.; Wei, Y.; Nemykin, V.N.; Zhdankin, V.V. Chem. Commun. 2012, 48, 10108-10110.
(Tosylimino)phenyl-lambda-3-iodane, PhINTs, as a Reagent for the Synthesis of Methyl Carbamates via Hofmann Rearrangement of Aromatic and Aliphatic Carboxamides. Yoshimura, A.; Luedtke, M.W.; Zhdankin, V.V. J. Org. Chem. 2012, 77, 2087-2091.
Potassium 4-iodylbenzenesulfonate: preparation, structure, and application as a reagent for oxidative iodination of arenes. Yusubov, M.S.; Yusubova, R.Y.; Nemykin, V.N.; Maskaev, A.V.; Geraskina, M.R.; Kirschning, A.; Zhdankin, V.V. Eur. J. Org. Chem. 2012, 5935-5942.
Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: a convenient recyclable reagent for catalytic oxidation. Zhu, C.; Yoshimura, A.; Wei Y.; Nemykin, V.N.; Zhdankin, V.V. Tetrahedron Lett. 2012, 53, 1438-1444.
Preparation and X-ray crystal
study of benziodoxaborole derivatives: new hypervalent iodine
heterocycles. Nemykin, V.N.; Maskaev, A.V.; Geraskina, M.R.; Yusubov,
M.S.; Zhdankin, V.V. Inorg. Chem.
2011, 50,
11263-11272.
SiO2-supported RuCl3/3-(dichloroiodo)benzoic acid: green catalytic
system for the oxidation of alcohols and sulfides in water. Zeng, X.-M.;
Chen, J.-M.; Yoshimura, A.; Middleton, K.; Zhdankin, V.V. RSC
Advances 2011, 1,
973-977.
Recyclable silica-supported iodoarene-RuCl3 bifunctional catalysts for
oxidation of alcohols and alkylarenes. Zeng, X.-M.; Chen, J.-M.;
Middleton, K.; Zhdankin, V.V. Tetrahedron
Lett. 2011, 52,
5652–5655.
o-Alkoxyphenyliminoiodanes:
Highly Efficient Reagents for Catalytic Aziridination of Alkenes and
Metal-Free Aminations of Organic Substrates. Yoshimura, A.; Nemykin,
V.N.; Zhdankin, V.V. Chem. Eur. J.
2011, 17,
10538-10541.
Iodonium salts in organic synthesis. Yusubov, M.S.; Maskaev, A.V.;
Zhdankin, V.V. ARKIVOC 2011,
(i), 370-409.
Preparation, X-ray Structure and Reactivity of 2-Iodylpyridines:
Recyclable Hypervalent Iodine(V) Reagents. Yoshimura, A.; Banek, C.T.;
Yusubov, M.S.; Nemykin, V.N.; Zhdankin, V.V. J.
Org. Chem. 2011, 76,
3812-3819.
Preparation and Reactivity of Polystyrene-supported Iodosylbenzene:
Convenient Recyclable Oxidizing Reagent and Catalyst. Chen, J.-M.; Zeng,
X.-M.; Middleton, K.; Yusubov, M.S.; Zhdankin, V.V. Synlett
2011, 1613-1617.
Organoiodine(V) Reagents in Organic Synthesis. Zhdankin, V.V. J.
Org. Chem. 2011,
76, 1185-1197. (a Perspective
with the journal cover art)
Facile preparation and reactivity of polystyrene-supported
(dichloroiodo)benzene: a convenient recyclable reagent for chlorinations
and oxidations. Chen, J.-M.; Zeng, X.-M.; Middleton, K.; Zhdankin,
V.V. Tetrahedron Lett. 2011,
52, 1952-1955.
Hofmann Rearrangement of Carboxamides Mediated by Hypervalent Iodine
Species Generated in situ from Iodobenzene and Oxone: Reaction Scope and
Limitations. Zagulyaeva, A.A.; Banek, C.T.; Yusubov, M.S.; Zhdankin,
V.V. Org. Lett. 2010,
12, 4644-4647.
Preparation and Reactivity of Polystyrene-Supported Iodosylbenzene
Sulfate, an Efficient Recyclable Oxidizing System. Chen, J.-M.; Zeng,
X.-M.; Zhdankin, V.V. Synlett
2010, 2771-2774.
m-Iodosylbenzoic acid as a
convenient recyclable hypervalent iodine oxidant for the synthesis of
α-iodoketones by oxidative iodination of ketones. Yusubov, M.S.;
Yusubova, R.Y.; Funk, T.V.; Chi, K.-W.; Kirschning, A.; Zhdankin, V.V. Synthesis
2010, 3681-3685.
Metalloporphyrin/Iodine(III)-Cocatalyzed Oxygenation of Aromatic
Hydrocarbons. Yoshimura, A.; Neu, H.M.; Nemykin, V.N.; Zhdankin, V.V. Adv.
Synth. Cat. 2010, 352,
1455-1460.
Transition Metal-mediated Oxidations Utilizing Monomeric Iodosyl- and
Iodylarene Species. Yusubov, M.S.; Nemykin, V.N.; Zhdankin, V.V. Tetrahedron
2010, 66,
5745-5752.
Development of New Recyclable Reagents and Catalytic Systems Based on
Hypervalent Iodine Compounds. Yusubov, M.S.; Zhdankin, V.V. Mendeleev
Commun. 2010, 20,
185-191.
A General and Convenient Preparation of
[Bis(trifluoroacetoxy)iodo]perfluoroalkanes and
[Bis(trifluoroacetoxy)iodo]arenes by Oxidation of Organic Iodides using
Oxone and Trifluoroacetic Acid. Zagulyaeva, A.A.; Yusubov, M.S.;
Zhdankin, V.V. J. Org. Chem.
2010, 75,
2119-2122.
Binuclear Iron(III) Phthalocyanine(μ-Oxodimer)-Catalyzed Oxygenation of
Aromatic Hydrocarbons with Iodosylbenzene Sulfate and Iodosylbenzene as
the Oxidants. Neu, H.M.; Yusubov, M.S.; Zhdankin, V.V.; Nemykin, V.N. Adv.
Synth. Cat. 2009,
351, 3168-3174.
Preparation, X-ray Structure, and Oxidative Reactivity of N-(2-Iodylphenyl)tosylamides
and 2-Iodylphenyl Tosylate: Iodylarenes Stabilized by Ortho-Substitution
with a Sulfonyl Group. Mailyan, A.K; Geraskin, I.M.; Nemykin, V.N.;
Zhdankin, V.V. J. Org. Chem.
2009, 74,
8444-8447.
Iodine(V)/Ruthenium(III)-Cocatalyzed Oxidations: A Highly Efficient
Tandem Catalytic System for the Oxidation of Alcohols and Hydrocarbons
with Oxone. Yusubov, M.S.; Zagulyaeva, A.A.; Zhdankin, V.V. Chem.
Eur. J. 2009, 15,
11091-11094.
Oligomeric iodosylbenzene sulfate, (PhIO)3•SO3: Convenient hypervalent
iodine reagent for oxidation of organic sulfides and alkenes. Yusubov,
M.S.; Yusubova, M.S.; Funk, T.V.; Chi, K.-W.; Zhdankin, V.V. Synthesis
2009, 2505-2508.
Self-assembly of hydroxy(phenyl)iodonium ions in acidic aqueous
solution: preparation, and X-ray crystal structures of oligomeric
phenyliodine(III) sulfates. Nemykin, V.N.; Koposov, A.Y.; Netzel, B.C.;
Yusubov, M.S.; Zhdankin, V.V. Inorg.
Chem. 2009, 48,
4908-4917.
Comparative Reactivity of Hypervalent Iodine Oxidants in
Metalloporphyrin-Catalyzed Oxygenation of Hydrocarbons: Iodosylbenzene
Sulfate and 2-Iodylbenzoic Acid Ester as Safe and Convenient
Alternatives to Iodosylbenzene. Geraskin, I.M.; Pavlova, O.; Neu, H.M.;
Yusubov, M.S.; Nemykin, V.N.; Zhdankin, V.V. Adv.
Synth. Cat. 2009, 351,
733-737.
Hypervalent Iodine(III) Reagents in Organic Synthesis. Zhdankin, V.V. ARKIVOC
2009, (i), 1-62.
Chemistry of Polyvalent Iodine. Zhdankin, V.V.; Stang, P.J. Chem.
Rev. 2008, 108,
5399-5358.
Preparation and X-ray crystal structure of 2-iodyl-N,N-dialkylaniline
oxides: first entry into the heterocyclic system of benziodoxazole.
Zhdankin, V.V.; Nemykin, V.N.; Karimov, R.R.; Kazhkenov, Z.M. Chem.
Commun. 2008,
6131-6133.
Organic iodine(V) compounds as terminal oxidants in iron(III)
phthalocyanine catalyzed oxidation of alcohols. Geraskin, I.M.; Luedtke,
M.W.; Neu, H.M.; Nemykin, V.N.; Zhdankin, V.V. Tetrahedron
Lett. 2008, 49,
7410-7412.
Synthesis of Tricyclic Phosphono Pyrrolidines via IMDAF: Experimental
and Theoretical Investigation of the Observed Stereoselectivity. Claeys,
D.D.; Moonen, K.; Roman, B.I.; Nemykin, V.N.; Zhdankin, V.V.; Waroquier,
M.; Speybroeck, V.V.; Stevens, C.V. J.
Org. Chem. 2008, 73,
7921-7927.
Heterocycles with Three or Four Heteroatoms Including At Least One
Phosphorus. Zhdankin, V.V. In Comprehensive Heterocyclic Chemistry III.
Katritzky, A.R.; Ramsden, C.A.; Scriven, E.F.V.; Taylor, R.J.K., Eds.;
Elsevier, Oxford, 2008, Vol. 6, Chapter 13, pp 583-602.
Preparation and X-ray Structures of 3-[Bis(trifluoroacetoxy)iodo]benzoic acid and 3-[Hydroxy(tosyloxy)iodo]benzoic acid, New Recyclable Hypervalent Iodine Reagents. Yusubov, M.S.; Funk, T.V.; Chi, K.-W.; Cha, E.-H.; Ghyung, H.K.; Kirschning, A.; Zhdankin, V.V. J. Org. Chem. 2008, 73, 295-297.
Preparation and Reactivity of Polymer-Supported
2-Iodylphenol Ethers, an Efficient Recyclable Oxidizing System. Karimov,
R.R.; Kazhkenov, Z.M.; Modjewski, M.J.; Peterson, E.M.; Zhdankin,
V.V. J. Org. Chem. 2007,
72, 8149-8151.
Preparation and Structure of Oligomeric
Iodosylbenzene Sulfate (PhIO)3•SO3: Stable and Water-soluble Analog of
Iodosylbenzene. Koposov, A.Y.; Netzel, B.C.; Yusubov, M.S.; Nemykin,
V.N.; Nazarenko, A.Y.; Zhdankin, V.V. Eur.
J. Org. Chem. 2007,
4475-4478.
Hypervalent Iodoarenes and Aryliodonium Salts.
Zhdankin, V.V. Science of Synthesis,
2007, 31,
Ch. 31.4.1, 161-234.
N-(2-Iodylphenyl)acylamides
- New Pentavalent Iodine Oxidizing Reagents. Ladziata, U.; Zhdankin,
V.V. Synlett 2007,
527-537.
m-Iodosylbenzoic Acid as a Convenient Recyclable
Reagent for Highly Efficient RuCl3-Catalyzed Oxidation of Alcohols to
Carbonyl Compounds. Yusubov, M.S.; Gilmkhanova, M.P.; Zhdankin, V.V.;
Kirschning, A. Synlett 2007,
563-566.
trans
Influences on Hypervalent Bonding of Aryl λ3-Iodanes: Their Stabilities
and Isodesmic Reactions of Benziodoxolones and Benziodazolones. Ochiai,
M.; Sueda, T.; Miyamoto, K.; Kiprof, P.; Zhdankin, V.V. Angew.
Chem. Int. Ed. 2006, 45,
8203-8206.
Hypervalent Iodine(V) Reagents in Organic Synthesis.
Ladziata, U.; Zhdankin, V.V. ARKIVOC
2006, (ix), 26-58.
Facile Preparation and Reactivity of
Polymer-Supported N-(2-Iodyl-phenyl)-acylamide,
an Efficient Oxidizing System. Ladziata, U.; Willging, J.; Zhdankin,
V.V. Org. Lett. 2006,
7, 167-170.
Highly Efficient RuCl3-Catalyzed Disproportionation
of (Diacetoxyiodo)benzene to Iodylbenzene and Iodobenzene; Leading to
the Efficient Oxidation of Alcohols to Carbonyl Compounds. Yusubov,
M.S.; Chi, K.-W.; Park, J.Y.; Karimov, R.; Zhdankin, V.V. Tetrahedron
Lett. 2006, 47,
6305-6308.
Synthesis and Oxidative Reactivity of New Chiral Hypervalent Iodine(V)
Reagents Based on (S)-Proline. Ladziata, U.; Carlson, J.; Zhdankin, V.V.
Tetrahedron Lett. 2006,
47, 6301-6304.
Preparation and Reductive Decomposition of
2-Iodoxybenzenesulfonic Acid; X-Ray Crystal Structure of 1H-1-Hydroxy-1,2,3-benziodoxathiole
3,3-dioxide. Koposov, A.Y.; Litvinov, D.N.; Zhdankin, V.V.; Ferguson,
M.J.; McDonald, R.; Tykwinski, R.R. Eur.
J. Org. Chem. 2006,
4791-4795.
2-Iodylphenol Ethers: Preparation, X-Ray Crystal
Structure, and Reactivity of New Hypervalent Iodine(V) Oxidizing
Reagents. Koposov, A.Y.; Karimov, R.R.; Geraskin, I.; Nemykin, V.N.;
Zhdankin, V.V. J. Org. Chem. 2006,
71, 8452-8458.
RuCl3-catalyzed Oxidation of Iodoarenes with
Peracetic Acid: New Facile Preparation of Iodylarenes. Koposov, A.Y.;
Karimov, R.R.; Pronin, A.A.; Skrupskaya, T.; Yusubov, M.S.; Zhdankin,
V.V. J. Org. Chem. 2006,
71, 9912-9914.
Selective Oxidation of Sulfides to Sulfoxides Using IBX-Esters. Koposov,
A.Y.; Zhdankin, V.V. Synthesis
2005, 22-25.
Derivatives of 2-Iodoxybenzenesulfonic Acid: New
Pseudocyclic Hypervalent Iodine Reagents. Zhdankin, V.V.; Goncharenko,
R.N.; Litvinov, D.N.; Koposov, A.Y. ARKIVOC
2005, (4), 8-18.
Benziodoxole-Based Hypervalent Iodine Reagents in
Organic Synthesis. Zhdankin, V.V. Curr.
Org. Synth. 2005, 2,
121-145.
Esters of 2-Iodoxybenzoic Acid (IBX-Esters):
Hypervalent Iodine Oxidizing Reagents with a Pseudobenziodoxole
Structure. Zhdankin, V.V.; Koposov, A.Y.; Litvinov, D.N.; Ferguson,
M.J.; McDonald, R.; Luu, T.; Tykwinski, R.R. J.
Org. Chem. 2005, 70,
6484-6491.
Intra- and Intermolecular Interactions in the Solid State Structure of
2-Iodylbenzenesulfonamides: a Heptacoordinated Organic Iodine(V)
Compound. Koposov, A.Y.; Nemykin, V.N.; Zhdankin, V.V. New
J. Chem. 2005, 29,
998-1000.
Synthesis, Structure and Chemoselective Reactivity of
N-(2-Iodylphenyl)-acylamides, Novel Hypervalent Iodine Reagents Bearing
Pseudo Six-membered Ring Scaffold. Ladziata, U.; Koposov, A.Y.; Lo,
K.Y.; Willging, J.; Nemykin, V.N.; Zhdankin, V.V. Angew.
Chem. Int. Ed. 2005, 44,
7127-7131.
Alkynyl Halides and Chalcogenides. Zhdankin, V.V. In
Comprehensive Organic Functional Group Transformations II.
Katritzky, A.R.; Taylor, R.J.K., Eds.; Elsevier, Oxford, 2004,
Vol. 2, Chapter 21, 1073-1114.
Preparation and Structure of 2-Iodoxybenzoate Esters: Soluble and Stable
Periodinane Oxidizing Reagents. Zhdankin, V.V.; Litvinov, D.N.; Koposov,
A.Y.; Luu, T.; Ferguson, M.J.; McDonald, R.; Tykwinski, R.R. J.
Chem. Soc., Chem. Commun. 2004, 106-107.
2-Iodoxybenzenesulfamides: New
Pseudobenziodoxole-Based Hypervalent Iodine Reagents. Koposov, A.Y.;
Litvinov, D.N.; Zhdankin, V.V. Tetrahedron
Lett. 2004, 45,
2719-2721.
4,4'-Bis(dichloroiodo)biphenyl and
3-(Dichloroiodo)benzoic Acid: New Recyclable Hypervalent Iodine Reagents
for Vicinal Halomethoxylation of Unsaturated Compounds. Yusubov, M.S.;
Drygunova, L.A.; Zhdankin, V.V. Synthesis
2004, 2289-2292.
Amino acid-derived iodobenzene dicarboxylates: Reagents for oxidative conversion of alkenes to amino acid esters. Koposov, A.Y.; Boyarskikh, V.V.; Zhdankin, V.V. Org. Lett. 2004, 6, 3613-3615.
C–C Bond Forming Reactions. Zhdankin, V.V. In Topics
in Current Chemistry, Vol. 224, Wirth, T., Ed.; Springer-Verlag,
Berlin Heidelberg, 2003, Chapter 4, pp. 99-136.
Preparation and Chemistry of Phosphorane-Derived Iodanes. Zhdankin,
V.V.; Maydanovych, O.; Herschbach, J.; Bruno, J.; Matveeva, E.D.;
Zefirov, N.S. J. Org. Chem. 2003, 68,
1018-1023.
IBX Amides: New Family of Hypervalent Iodine Reagents. Zhdankin, V.V.;
Koposov, A.Y.; Netzel, B.C.; Yashin, N.V.; Rempel, B.P.; Ferguson, M.J.;
Tykwinski, R.R. Angew. Chem. Int. Ed. 2003, 42,
2194-2196. (Placed on Angew. Chem. Hot Articles Website).
Synthesis and Structure of Amino Acid-Derived Benziodazoles: New
Hypervalent Iodine Heterocycles. Zhdankin, V.V.; Koposov, A.Y.; Su, L.;
Boyarskikh, V.V.; Netzel, B.C.; Young, V.G. Org. Lett. 2003,
5, 1583-1586. (Placed on ACS Hot Articles Website).
Recent Developments in the Chemistry of Polyvalent Iodine Compounds.
Zhdankin, V.V.; Stang, P.J. Chem. Rev. 2002, 102,
2523-2584.
Complexes of Hypervalent Iodine Compounds with Nitrogen Ligands. Zhdankin, V.V.; Koposov, A.Y.; Yashin, N.V. Tetrahedron Lett. 2002, 42, 5735-5737.
Preparation, Structure, and Unexpected Chemistry of
Phosphoranyl Derived Benziodoxoles. Zhdankin, V.V.; Maydanovych, O.;
Herschbach, J.; Tykwinski, R.R.; McDonald, R. J. Am. Chem. Soc.
2002, 124, 11614-11615.
Functionalization of Buckminsterfullerene by Hypervalent Iodine Reagents. Zhdankin, V.V.; Hanson, K.J.; Koposov, A.E.; Blomquist, E.; Tykwinski, R.R. Mendeleev Commun. 2001, 51-52.
Secondary Bonding-Directed Self-Assembly of Amino Acid Derived Benziodazoles: Synthesis and Structure of Novel Hypervalent Iodine Macrocycles. Zhdankin, V.V.; Koposov, A.E.; Smart, J.T.; Tykwinski, R.R.; McDonald, R.; Morales-Izquierdo, A. J. Am. Chem. Soc. 2001, 123, 4095-4096.
Books
Hypervalent
Iodine Chemistry: Preparation, Structure, and Synthetic Applications
of Polyvalent Iodine Compounds. Zhdankin, V.V. Wiley:
Chichester, 2013; ISBN: 978-1-118-34103-2.
Handbook of Heterocyclic
Chemistry, 3rd Edition. Katritzky, A.R.; Ramsden, C.A.; Joule,
J.A.; Zhdankin, V.V. Elsevier, Oxford, 2010; ISBN 0080958435.
Hypervalent Iodine Chemistry - Modern Developments in Organic
Synthesis. Top. Curr. Chem. 224. Wirth, T.; Ochiai, M.;
Zhdankin, V. V.; Koser, G. F.; Tohma, H.; Kita, Y. Springer: Berlin,
2003.
Organic Chemistry: a Two-Semester
Course of Essential Organic Chemistry. Zhdankin, V.; Grundt P.
Cognella: San Diego, 2018.
Edited
Books
Comprehensive Heterocyclic Chemistry III, Volume 5 (10 chapters): “Triazoles,
Oxadiazoles, Thiadiazoles and their Fused Carbocyclic Derivatives,” V.V.
Zhdankin, Ed.; Elsevier, Oxford, 2008.
Comprehensive Heterocyclic Chemistry III, Volume 6 (18 chapters): “Other
Five-Membered Rings with Three or More Heteroatoms and their Fused
Carbocyclic Derivatives,” V.V. Zhdankin, Ed.; Elsevier, Oxford, 2008.